(d) The chlorine dioxide generator shall be equipped with a chlorine dioxide analyzer to measure the strength of the solution leaving the generator.(e) Generators which use solid chlorite will not be allowed.
(3) Chlorine Dioxide Feed and Storage System
(a) Chlorine Dioxide Feed system.
(i) Use fiberglass reinforced vinyl ester plastic (FRP) or high density linear polyethylene (HDLPE) tanks with no insulation.
(ii) If centrifugal pumps are used, provide Teflon packing material. Pump motors must be totally enclosed, fan-cooled, equipped with permanently sealed bearings, and equipped with double mechanical seals or other means to prevent leakage.
(iii) Provide chlorinated PVC, vinyl ester or Teflon piping material. Do not use carbon steel or stainless steel piping systems.
(iv) Provide glass view ports for the reactor if it is not made of transparent material.
(v) Provide flow monitoring on all chemical feed lines, dilution water lines, and chlorine dioxide solution lines.
(vi) Provide a means to verify calibrated feed flow to each application feed point.
(vii) Control air contact with chlorine dioxide solution to limit potential for explosive concentrations building up within the feed facility.
(viii) All chlorite solutions shall have concentrations less than 30%. Higher strength solutions are susceptible to crystallization and stratification.
(b) Chlorine Dioxide Storage and Operating Area. The following requirements apply to the chlorite storage and chlorine dioxide day tank area.
(i) The chlorine dioxide facility shall be physically located in a separate room from other water treatment plant operating areas.
(ii) The chlorine dioxide area shall have a ventilation system separate from other operating areas.
(iii) Provision shall be made to ventilate the chlorine dioxide facility area and maintain the ambient air chlorine dioxide concentrations below the Permissible Exposure Limit (PEL).
(A) The ventilating fan(s) take suction near the floor, as far as practical from the door and air inlet, with the point of discharge so located as not to contaminate air inlets of any rooms or structures.
(B) Air inlets are provided near the ceiling.
(C) Air inlets and outlets shall be louvered.
(D) Separate switches for the fans are outside and near the entrance of the facility.
(iv) The area housing chlorine dioxide facility shall be constructed of non-combustible materials such as concrete.
(v) There shall be an ambient air chlorine dioxide sensor in the vicinity of the chlorine dioxide operating area. The ambient air chlorine dioxide readouts and alarm or warning light shall be audible and visible in the operating area and on the outside of the door to the operating area. The design shall include distinguishing audible alarms that are triggered by the ambient air chlorine dioxide sensor readings.
(vi) There shall be observation windows through which the operating area can be observed from outside the room to ensure operator safety.
(vii) Manual switches to the light in the operating area shall be located outside the door to the room.
(viii) There shall be an emergency shower and eyewash outside and close to the door to the operating area.
(ix) An emergency shutoff control to shut flows to the generator shall be located outside the operating area.
(x) The design shall minimize the possibility of chlorite leaks.
(xi) The chlorite tank and chlorine dioxide solution tank shall be vented to the outdoors away from any operating areas.
(xii) Gaseous chlorine feed to the chlorine dioxide generator shall enter the chlorine dioxide facility area through lines which can only feed to vacuum.
(xiii) The floor of the chlorine dioxide facility area shall slope to a sump.
(xiv) There shall not be any open drains in the chlorine dioxide operating area.
(xv) Provide secondary containments with sumps for chlorine dioxide storage, and chlorine dioxide solutions which can hold the entire volume of these vessels. This containment shall prevent these solutions from entering the rest of the operating area.
(xvi) Provide wash-down water within the operating area.
(xvii) The operating area shall be designed to avoid direct exposure to sunlight, UV light, or excessive heat.
(4) Other Design Criteria.
(a) Provide secondary containment, a sump, wash-down water, and a shower and eyewash at the bulk delivery transfer point.
(b) Finished water shall be used for chlorine dioxide generation.
(c) The finished water line to the chlorine dioxide generator shall be protected with a high hazard assembly.
(d) Provide a water supply near the storage and handling area for cleanup.
(e) The parts of the chlorine dioxide system in contact with the strong oxidizing or acid solutions shall be of inert material.
(f) The design shall provide the capability to shut off the chlorine dioxide operation remotely, i.e., from a location that is outside of the chlorine dioxide operating area.
(5) Operation and Maintenance.
(a) Do not store or handle combustible or reactive materials, such as acids, reduced metals, or organic material, in the chlorine dioxide operating area.
(b) Store chemicals in clean, closed, non-translucent containers.
(c) Personal protective equipment and first aid kits shall be stored at a nearby location that is outside the chlorine dioxide facility area.